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Article Dans Une Revue Catalysis Science & Technology Année : 2021

Ruthenium-catalysed oxidative coupling of vinyl derivatives and application in tandem hydrogenation

Résumé

The first ruthenium-catalyzed oxidative homo- and cross-coupling of exclusive vinyl derivatives giving highly valued 1,3-diene building blocks is reported. The catalytic system is based on readily available reagents and it mainly delivers the E,E isomer. This methodology also enables the synthesis of adipic acid ester derivatives in a one-pot fashion after in situ ruthenium-catalyzed hydrogenation.

Domaines

Chimie Catalyse
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Dates et versions

hal-03331321 , version 1 (15-09-2021)

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Naba Abuhafez, Hervé Ruffin, Raghu Kamaraj, Christian Bruneau, Rafael Gramage-Doria. Ruthenium-catalysed oxidative coupling of vinyl derivatives and application in tandem hydrogenation. Catalysis Science & Technology, 2021, 11 (17), pp.5772-5776. ⟨10.1039/d1cy01282g⟩. ⟨hal-03331321⟩
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