A test site located along a 12-lane motorway east of Montpellier, France, is used to evaluate the potential of biomagnetic monitoring on traffic-related particulate matter (PM) to parametrize a computational fluid dynamics (CFD) simulation of the local airflow. Two configurations were established on the site with three vegetated flat-top earth berms of a basic design, and a fourth one was located windward to the traffic roofed with a 4-m-high precast concrete wall. As a first step, PM deposition simultaneously on plant leaves, on low-cost passive artificial filters, and on soils was estimated from proxies supplied by magnetic and X-ray fluorescence measurements on both sides of the motorway. These latter revealed that traffic-related pollutants are present on soils samples highlighted with a clear fingerprint of combustion residues, and wears of breaks, vehicles, and highway equipment. Maximum PM accumulations were detected in the lee of the berm-wall combination, while no significant deposition was observed on both sides of the flat-top earth berms. These results are in line with measurements from PM µ-sensors operated by the regional stateapproved air quality agency. Finally, we compared the experimental measurements with the outcomes of a computational fluid dynamics (CFD) modeling based on the Reynolds-Averaged Navier-Stokes (RANS) equations that consider the traffic-induced momentum and turbulence. The CFD modeling matches the experimental results by predicting a recirculated flow in the near wake of the berm-wall combination that enhances the PM concentration, whereas the flat-top berm geometry does not alter the pollutants' transport and indeed contributes to their atmospheric dispersion.