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Article Dans Une Revue Molecules Année : 2020

Ferrocenyl phosphorhydrazone dendrimers dynthesis, and electrochemical and catalytic properties

Résumé

The discovery of ferrocene is often associated with the rapid growth of organometallic chemistry. Dendrimers are highly branched macromolecules that can be functionalized at will at all levels of their structure. The functionalization of dendrimers with ferrocene derivatives can be carried out easily as terminal functions on the surface, but also at the core, or at one or several layers inside the structure. This review will focus on phosphorhydrazone dendrimers functionalized with ferrocene derivatives, on the surface, at the core, at all layers or within a single layer inside the structure. The first part will describe the synthesis; the second part will concern the electrochemical properties; and the last part will give several examples concerning catalysis, with complexes of ferrocenyl phosphines used as terminal functions of dendrimers.
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Dates et versions

hal-02448427 , version 1 (09-11-2020)

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Cédric-Olivier Turrin, Eric Manoury, Anne-Marie Caminade. Ferrocenyl phosphorhydrazone dendrimers dynthesis, and electrochemical and catalytic properties. Molecules, 2020, 25 (3), pp.447. ⟨10.3390/molecules25030447⟩. ⟨hal-02448427⟩
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