Pincer versus Pseudo-Pincer: Isomerism in Palladium(II) Complexes bearing κ3C,S,C ligands
Résumé
In NHC pincer complexes incorporatig a hemilabile donor site, there exists an equilibrium between the true pincer form and a pseudopincer coordination isomer. The influence of the NHC moieties on this isomerism has been studied by DFT calculations.
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