We study the geometry of a family of Lie groups, which contained the classical affine Lie groups, endowed with an exact left invariant symplectic form. We show that this family is closed by symplectic reduction and symplectic double extension in the sense of Dardié and Medina. We prouve also that these groups are endowed with two transverse left invariant Lagrangian ( resp. Symplectic ) foliations. This implies that these groups admit a left invariant torsion free symplectic connection.