La Substitution into the Melilite Derivative Ca<sub>5</sub>Ga<sub>6</sub>O<sub>14</sub> : Prediction, Synthesis and Ionic Conductivity - Archive ouverte HAL
Article Dans Une Revue Inorganic Chemistry Année : 2024

La Substitution into the Melilite Derivative Ca5Ga6O14 : Prediction, Synthesis and Ionic Conductivity

George Darling
Matthew Dyer

Résumé

Layered melilite-type gallates of general formula RE1+xAE1-xGa3O7+x/2 are of interest for their ability to host mobile interstitial oxide ions in [Ga3O7+x] layers. The crystal structure of Ca5Ga6O14 is closely related to melilite, with [Ga3O7] layers stacked in a more complex way to accommodate an additional 0.5 interlayer cations per formula unit, suggesting the potential for similar oxide ion conduction behaviour. We used a computational approach to identify the most promising routes to interstitial oxide incorporation into Ca5Ga6O14, leading to an experimental investigation of the system Ca5-xGa6O14+x/2. Single-phase materials were obtained in the range 0 ≤ x ≤ 0.25 by solid state reactions, producing an ~40× increase in ionic conductivity at 800°C. This limited compositional range presents a challenge for characterisation of the charge-compensating defects. The La substituents were observed directly by X-ray diffraction and STEM-EDX, and a combination of different structural characterization techniques and DFT calculations indicated the presence of interstitial oxide ions indirectly, explaining the conductivity response. As higher carrier concentrations (x > 0.25) are apparently inaccessible in this system, we conclude that its potential as a useful oxide ion conductor is more limited than that of established melilite materials such as La1+xCa1-xGa2O7+x/2
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samedi 27 septembre 2025
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hal-04712206 , version 1 (27-09-2024)

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Haytem Bazzaoui, Meigeng Gao, Olivier Hernandez, Sébastien Chenu, Lijun He, et al.. La Substitution into the Melilite Derivative Ca5Ga6O14 : Prediction, Synthesis and Ionic Conductivity. Inorganic Chemistry, 2024, ⟨10.1021/acs.inorgchem.4c03172⟩. ⟨hal-04712206⟩
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