Microwave assisted benzyl alcohol oxidation using iron particles on furfuryl alcohol derived supports - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Catalysis Communications Année : 2017

Microwave assisted benzyl alcohol oxidation using iron particles on furfuryl alcohol derived supports

Pepijn Prinsen
  • Fonction : Auteur
Alfonso Yepez
  • Fonction : Auteur
Guobao Xu
  • Fonction : Auteur
Christophe Len
  • Fonction : Auteur
  • PersonId : 909367
Rafael Luque

Résumé

This work compares the catalytic activity of iron catalysts supported on porous furfuryl alcohol derived resins for the selective conversion of benzyl alcohol to benzaldehyde using hydrogen peroxide as the oxidant and assisted by microwave irradiation. The catalysts were prepared mechanochemically by ball-milling in the dry state. Initial results showed that the pressure in the reaction medium and the oxidant load are essential to achieve significant conversions. An apparent minimum catalyst load of 0.05 mol% Fe was required for significant reactivity at 132 °C.

Domaines

Chimie
Fichier principal
Vignette du fichier
Catalysis Communications 2018, 104 67.pdf (279.5 Ko) Télécharger le fichier
Origine Fichiers éditeurs autorisés sur une archive ouverte

Dates et versions

hal-04269411 , version 1 (03-11-2023)

Identifiants

Citer

Floriane Mangin, Pepijn Prinsen, Alfonso Yepez, Muhammad Rehan Hasan Shah Gilani, Guobao Xu, et al.. Microwave assisted benzyl alcohol oxidation using iron particles on furfuryl alcohol derived supports. Catalysis Communications, 2017, 104, pp.67 - 70. ⟨10.1016/j.catcom.2017.10.003⟩. ⟨hal-04269411⟩
54 Consultations
29 Téléchargements

Altmetric

Partager

Gmail Mastodon Facebook X LinkedIn More