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Article Dans Une Revue Chemical Communications Année : 2023

Cobalt tris(4-vinylphenyl)corrole: out of the frying pan into the polymer

Louise Hespel
Laurent Lebrun

Résumé

A novel cobalt corrole bearing 4-vinylphenyl groups at the 5,10,15-meso-positions of the macrocycle has been synthesized from tris(4-bromophenyl)corrole using a Suzuki coupling reaction. The spectral and electrochemical properties are reported in CH2Cl2 along with its ability to form a highly stable six-coordinate complex and cross-linked corrole-based polymer in a 59% yield.
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Dates et versions

hal-04252458 , version 1 (20-10-2023)

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Nicolas Desbois, W. Ryan Osterloh, Dimitri Sabat, Camille Monot, Stéphane Brandès, et al.. Cobalt tris(4-vinylphenyl)corrole: out of the frying pan into the polymer. Chemical Communications, 2023, 59 (15), pp.2098-2101. ⟨10.1039/d2cc06872a⟩. ⟨hal-04252458⟩
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