Cobalt tris(4-vinylphenyl)corrole: out of the frying pan into the polymer
Résumé
A novel cobalt corrole bearing 4-vinylphenyl groups at the 5,10,15-meso-positions of the macrocycle has been synthesized from tris(4-bromophenyl)corrole using a Suzuki coupling reaction. The spectral and electrochemical properties are reported in CH2Cl2 along with its ability to form a highly stable six-coordinate complex
and cross-linked corrole-based polymer in a 59% yield.
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Cobalt Tris(4-Vinylphenyl)Corrole_CC-COM-12-2022-006872_HAL.pdf (1.1 Mo)
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