Electrochemical fabrication of nanowires poly (Indole-6-carboxylic acid) adorned with nanorod MnO2 for evaluation of its capacitive properties - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Electrochimica Acta Année : 2023

Electrochemical fabrication of nanowires poly (Indole-6-carboxylic acid) adorned with nanorod MnO2 for evaluation of its capacitive properties

Résumé

A poly(indole-6-carboxy acid) nanowire composite with & beta;-MnO2 nanorod (6-PICA|& beta;-MnO2-NRs) was prepared by an electrochemical method and hydrothermal. The incorporation of & beta;-MnO2-NRs and the formation of 6-PICA nanowires are verified by SEM, TEM, Raman, powder XRD, and XPS, where the nanowires perform as an electroactive material and also as an environment to disperse the & beta;-MnO2 nanorods, at different concentrations. The study as a supercapacitor material shows that the specific capacitance of 6-PICA|& beta;-MnO2-NRs is 61.35 mFcm  2, higher than that of 6-PICA (43.01 mFcm  2) deposited on the ITO conductive glass electrode. These results indicate that the presence of pure phase & beta;-MnO2 in the form of nanostructure enhances the specific capacitance and ion diffusion in the charge-discharge process of 6-PICA at higher current densities without losing significant stability after 1000 cycles.

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Chimie
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Dates et versions

hal-04214975 , version 1 (22-09-2023)

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J. Lorca-Ponce, Jonathan Cisterna, Linda Cattin, Jean-Christian Bernède, G. Louarn, et al.. Electrochemical fabrication of nanowires poly (Indole-6-carboxylic acid) adorned with nanorod MnO2 for evaluation of its capacitive properties. Electrochimica Acta, 2023, 464, pp.142937. ⟨10.1016/j.electacta.2023.142937⟩. ⟨hal-04214975⟩
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