The three channels of many-body perturbation theory: $GW$, particle-particle, and electron-hole $T$-matrix self-energies - Archive ouverte HAL
Article Dans Une Revue The Journal of Chemical Physics Année : 2023

The three channels of many-body perturbation theory: $GW$, particle-particle, and electron-hole $T$-matrix self-energies

Résumé

We derive the explicit expression of the three self-energies that one encounters in many-body perturbation theory: the well-known $GW$ self-energy, as well as the particle-particle and electron-hole $T$-matrix self-energies. Each of these can be easily computed via the eigenvalues and eigenvectors of a different random-phase approximation (RPA) linear eigenvalue problem that completely defines their corresponding response function. For illustrative and comparative purposes, we report the principal ionization potentials of a set of small molecules computed at each level of theory.
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Dates et versions

hal-04201951 , version 1 (11-09-2023)

Identifiants

Citer

Roberto Orlando, Pina Romaniello, Pierre-François Loos. The three channels of many-body perturbation theory: $GW$, particle-particle, and electron-hole $T$-matrix self-energies. The Journal of Chemical Physics, 2023, 159 (18), pp.184113. ⟨10.1063/5.0176898⟩. ⟨hal-04201951⟩
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