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Article Dans Une Revue Chemical Communications Année : 2023

Nanotubule inclusion in the channels formed by a six-fold interpenetrated, triperiodic framework

Résumé

When reacted together with uranyl ion under solvo-hydrothermal conditions, a bis(pyridiniumcarboxylate) zwitterion (L) and tricarballylic acid (H3tca) give the complex [NH4]2[UO2(L)2][UO2(tca)]4·2H2O (1). The two ligands are segregated into different units, an anionic nanotubule for tca3– and a six-fold interpenetrated cationic framework with lvt topology for L. The entangled framework defines large channels which contain the square-profile nanotubules. Complex 1 has a photoluminescence quantum yield of 19% and its emission spectrum shows the superposition of the signals due to the two independent species.
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Dates et versions

hal-04170568 , version 1 (25-07-2023)

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Sotaro Kusumoto, Youssef Atoini, Yoshihiro Koide, Kittipong Chainok, Shinya Hayami, et al.. Nanotubule inclusion in the channels formed by a six-fold interpenetrated, triperiodic framework. Chemical Communications, In press, ⟨10.1039/D3CC02636A⟩. ⟨hal-04170568⟩
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