We deal with two complementary questions about approximation properties of ReLU networks. First, we study how the uniform quantization of ReLU networks with real-valued weights impacts their approximation properties. We establish an upper-bound on the minimal number of bits per coordinate needed for uniformly quantized ReLU networks to keep the same polynomial asymptotic approximation speeds as unquantized ones. We also characterize the error of nearest-neighbour uniform quantization of ReLU networks. This is achieved using a new lower-bound on the Lipschitz constant of the map that associates the parameters of ReLU networks to their realization, and an upper-bound generalizing classical results. Second, we investigate when ReLU networks can be expected, or not, to have better approximation properties than other classical approximation families. Indeed, several approximation families share the following common limitation: their polynomial asymptotic approximation speed of any set is bounded from above by the encoding speed of this set. We introduce a new abstract property of approximation families, called infinite-encodability, which implies this upper-bound. Many classical approximation families, defined with dictionaries or ReLU networks, are shown to be infinite-encodable. This unifies and generalizes several situations where this upper-bound is known.