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Article Dans Une Revue Mendeleev Communications Année : 2022

Phosphatetrasilatricyclo[2.1.0.02,5]pentane

Résumé

The phosphatetrasilatricyclo[2.1.0.02,5]pentane cage compound was synthesized by the reaction of the tetrasilacyclobutadiene dianion dipotassium salt precursor with PCl3. The structure, bonding nature, and mechanism of formation of the title compound were studied both experimentally (NMR, X-ray) and computationally (DFT).

Dates et versions

hal-03660695 , version 1 (06-05-2022)

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Vladimir Ya. Lee, Takahiko Meguro, Olga Gapurenko, Ruslan Minyaev, Vladimir Minkin, et al.. Phosphatetrasilatricyclo[2.1.0.02,5]pentane. Mendeleev Communications, 2022, 32 (1), pp.33-34. ⟨10.1016/j.mencom.2022.01.009⟩. ⟨hal-03660695⟩
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