Phosphatetrasilatricyclo[2.1.0.02,5]pentane

The phosphatetrasilatricyclo[2.1.0.02,5]pentane cage compound was synthesized by the reaction of the tetrasilacyclobutadiene dianion dipotassium salt precursor with PCl3. The structure, bonding nature, and mechanism of formation of the title compound were studied both experimentally (NMR, X-ray) and computationally (DFT).

Mots clés

DFT calculations Housene Phosphorus Silicon Tricyclo[2.1.0.025]pentane X-ray diffraction

Domaines

Chimie de coordination

Marie-Hélène Gulli : Connectez-vous pour contacter le contributeur

https://hal.science/hal-03660695

Soumis le : vendredi 6 mai 2022-10:36:46

Dernière modification le : jeudi 18 juillet 2024-10:52:26

Dates et versions

hal-03660695 , version 1 (06-05-2022)

Identifiants

HAL Id : hal-03660695 , version 1
DOI : 10.1016/j.mencom.2022.01.009

Citer

Vladimir Ya. Lee, Takahiko Meguro, Olga Gapurenko, Ruslan Minyaev, Vladimir Minkin, et al.. Phosphatetrasilatricyclo[2.1.0.02,5]pentane. Mendeleev Communications, 2022, 32 (1), pp.33-34. ⟨10.1016/j.mencom.2022.01.009⟩. ⟨hal-03660695⟩

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