Self-Assembly of Functionalized Lipophilic Guanosines into Cation-Free Stacked Guanine-Quartets - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Journal of Organic Chemistry Année : 2021

Self-Assembly of Functionalized Lipophilic Guanosines into Cation-Free Stacked Guanine-Quartets

Résumé

The hierarchical self-assembly of various lipophilic guanosines exposing either a phenyl or a ferrocenyl group in the C(8) position was investigated. In a solution, all the derivatives were found to self-assemble primarily into isolated guanine (G)-quartets. In spite of the apparent similar bulkiness of the two substituents, most of the derivatives form disordered structures in the solid state, whereas a specific 8-phenyl derivative self-assembles into an unprecedented, cation-free stacked G-quartet architecture.
Fichier principal
Vignette du fichier
islandora_148788.pdf (6.55 Mo) Télécharger le fichier
Origine : Publication financée par une institution

Dates et versions

hal-03633337 , version 1 (06-04-2022)

Identifiants

Citer

Marilena Campitiello, Alessio Cremonini, Marco A. Squillaci, Silvia Pieraccini, Artur Ciesielski, et al.. Self-Assembly of Functionalized Lipophilic Guanosines into Cation-Free Stacked Guanine-Quartets. Journal of Organic Chemistry, 2021, 86 (15), pp.9970-9978. ⟨10.1021/acs.joc.1c00502⟩. ⟨hal-03633337⟩
24 Consultations
33 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More