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Article Dans Une Revue Chemical Communications Année : 2021

A High Dimensional Oxysulfide Built from Large Iron-based Clusters with Partial Charge-Ordering

Résumé

Herein we report the original Ba10Fe7.75Zn5.25S18Si3O12 oxysulfide which crystallizes in a new structural type. Contrary to the usual oxychalcogenides, it crystallizes with a non-centrosymmetric 3D spatial network structure built from large magnetic clusters consisting of twelve (Fe2+/3+/Zn)S3O tetrahedra decorating a central Fe2+S6 octahedron and exhibiting a spin glass state
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hal-03457569 , version 1 (30-11-2021)

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Batoul Almoussawi, Angel Arévalo-López, Pardis Simon, Houria Kabbour. A High Dimensional Oxysulfide Built from Large Iron-based Clusters with Partial Charge-Ordering. Chemical Communications, 2021, 57 (89), pp.11859-11862. ⟨10.1039/D1CC04501F⟩. ⟨hal-03457569⟩
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