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Article Dans Une Revue Tetrahedron Letters Année : 2005

Anodic oxidation of chiral sulfinylamines: a new route to highly diastereoselective a-alkylation of piperidine

Résumé

The anodic oxidation of some chiral non-racemic N-arylsulfinyl piperidines was investigated and for the first time a methoxylated sulfinyl piperidines were obtained. The so-formed compounds are equivalent of chiral N-sulfinyliminiums and used as new intermediates for the preparation of chiral a-substituted piperidine derivatives in good yield and diastereoselectivity

Domaines

Chimie organique
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Dates et versions

hal-03385953 , version 1 (19-10-2021)

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Serge Turcaud, Thierry Martens, Emma Sierecki, Joelle Pérard-Viret, Jacques Royer. Anodic oxidation of chiral sulfinylamines: a new route to highly diastereoselective a-alkylation of piperidine. Tetrahedron Letters, 2005, 46 (31), pp.5131-5134. ⟨10.1016/j.tetlet.2005.05.123⟩. ⟨hal-03385953⟩

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