Anodic oxidation of chiral sulfinylamines: a new route to highly diastereoselective a-alkylation of piperidine
Résumé
The anodic oxidation of some chiral non-racemic N-arylsulfinyl piperidines was investigated and for the first time a methoxylated
sulfinyl piperidines were obtained. The so-formed compounds are equivalent of chiral N-sulfinyliminiums and used as new
intermediates for the preparation of chiral a-substituted piperidine derivatives in good yield and diastereoselectivity
Domaines
Chimie organiqueOrigine | Fichiers produits par l'(les) auteur(s) |
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