Octahedral Hexachloro Environment of Dy3+ with Slow Magnetic Relaxation and Luminescent Properties - Archive ouverte HAL Access content directly
Journal Articles European Journal of Inorganic Chemistry Year : 2021

Octahedral Hexachloro Environment of Dy3+ with Slow Magnetic Relaxation and Luminescent Properties

Abstract

The compound [BiCNIm]3[DyCl6] was synthesized from a nitrile-functionalized imidazolium ionic liquid [BiCNIm][Cl] and DyCl3 ⋅ 6H2O in acetonitrile using solvothermal conditions. Structural characterization reveals that the Dy3+ ions are in a quasi-regular octahedral environment, formed by six chloride anions. The magnetic study indicates that this mononuclear compound exhibits a Single Ion Magnet behaviour. This behaviour is compared to that of other mononuclear compounds containing Dy3+ ions in various octahedral environment.
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Dates and versions

hal-03268319 , version 1 (24-06-2021)

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Cite

Nesrine Benamara, Mayoro Diop, Cedric Leuvrey, Marc Lenertz, Pierre Gilliot, et al.. Octahedral Hexachloro Environment of Dy3+ with Slow Magnetic Relaxation and Luminescent Properties. European Journal of Inorganic Chemistry, 2021, 22, pp.2099-2107. ⟨10.1002/ejic.202100143⟩. ⟨hal-03268319⟩
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