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Article Dans Une Revue Journal of Applied Crystallography Année : 2020

Bragg Coherent Imaging of nanoprecipitates: role of superstructure reflections

Imagerie par diffraction des rayons X cohérents de nanoprécipités: rôle des réflexions de surstructure

Résumé

Coherent precipitation of ordered phases is responsible for providing exceptional high temperature mechanical properties in a wide range of compositionally complex alloys (CCAs). Ordered phases are also essential to enhance the magnetic or catalytic properties of alloyed nanoparticles. The present work aims at demonstrating the relevance of Bragg coherent diffraction imaging (BCDI) to study bulk and thin film samples or isolated nanoparticles containing coherent nanoprecipitates / ordered phases. Crystals of a few tens of nanometres are modelled with realistic interatomic potentials and relaxed after introduction of coherent ordered nanoprecipitates. Diffraction patterns from fundamental and superstructure reflections are calculated in the kinematic approximation and used as input to retrieve the strain fields using algorithmic inversion. We first tackle the case of single nanoprecipitates and show that the strain field distribution from the ordered phase is retrieved very accurately. Then, we investigate the influence of the order parameter S on the strain field retrieved from the superstructure reflections and evidence that a very accurate strain distribution can be retrieved for partially ordered phases with large and inhomogeneous strains. In a subsequent section, we evaluate the relevance of BCDI for the study of systems containing many precipitates and demonstrate that the technique is relevant for such systems. Finally, we discuss the experimental feasibility of using BCDI to image ordered phases, in the light of the new possibilities offered by the 4 th generation synchrotron sources.
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Dates et versions

hal-03228501 , version 1 (18-05-2021)

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  • HAL Id : hal-03228501 , version 1

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Maxime Dupraz, Steven J Leake, Marie-Ingrid Richard. Bragg Coherent Imaging of nanoprecipitates: role of superstructure reflections. Journal of Applied Crystallography, 2020, 53 (5), pp.1353-1369. ⟨hal-03228501⟩
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