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Article Dans Une Revue Angewandte Chemie International Edition Année : 2015

Velocity of a Molecule Evaporated from a Water Nanodroplet: Maxwell-Boltzmann Statistics versus Non-Ergodic Events

Résumé

The velocity distribution of water molecules evaporated from a mass-selected protonated water nanodroplet after a collision-induced electronic excitation is reported. In their Communication (DOI: 10.1002/anie.201505890), M. Farizon et al. show that besides the Maxwell–Boltzmann statistics behavior, a distinct high-velocity contribution provides evidence for molecular evaporation before complete energy redistribution, corresponding to non-ergodic events.
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Dates et versions

hal-03171505 , version 1 (17-03-2021)

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Hassan Abdoul-Carime, Francis Berthias, Linda Feketeová, Mathieu Marciante, Florent Calvo, et al.. Velocity of a Molecule Evaporated from a Water Nanodroplet: Maxwell-Boltzmann Statistics versus Non-Ergodic Events. Angewandte Chemie International Edition, 2015, 54 (49), pp.14685-14689. ⟨10.1002/anie.201505890⟩. ⟨hal-03171505⟩
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