Quantitative and specific recovery of natural organic and mineral sulfur for (multi-)isotope analysis - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Organic Geochemistry Année : 2020

Quantitative and specific recovery of natural organic and mineral sulfur for (multi-)isotope analysis

Résumé

Deciphering the role of sulfur in biogeochemical cycles strongly relies on its stable isotope composition, which ultimately depends on the ability to quantitatively recover different sulfur species from geological samples. For decades most studies have been restricted to the 34S/32S composition of bulk samples, using simple methods based on the analysis of SO2 released by sample combustion combined to mass spectrometry. The wet chemistry procedures required to selectively extract specific sulfur species were generally avoided due to their tediousness and inefficiency for some complex matrices, especially when targeting organic sulfur. With the recent advent of multi-isotope studies (investigating the minor sulfur stable isotopes 33S and 36S) which rely either on the analysis of sulfur as SF6, or on the use of secondary ion or multi-collector inductively coupled plasma mass spectrometry, wet chemistry-based preparation procedures were brought back to the stage with a renewed interest in developing procedures better adapted to the investigation of specific sulfur species. Here we propose a new stepwise chemical procedure for the quantitative recovery and multi-isotope analysis of organic sulfur from both solvent soluble (total lipid extract) and insoluble (kerogen) fractions, based on a wet oxidation by sodium hypochlorite. This procedure also allows the multi-isotope analysis of inorganic sulfur species (elemental sulfur, sulfates and sulfides) in the same sample. Its application to different well-known petroleum source rocks and to an oil demonstrates its relevance for disentangling the interactions between the different sulfur pools and for shedding new light on the sulfur biogeochemical cycle.
Fichier principal
Vignette du fichier
islandora_101512.pdf (1.03 Mo) Télécharger le fichier
Origine : Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-02963254 , version 1 (09-10-2020)

Identifiants

Citer

I. Jovovic, V. Grossi, Pierre Adam, L. Simon, I. Antheaume, et al.. Quantitative and specific recovery of natural organic and mineral sulfur for (multi-)isotope analysis. Organic Geochemistry, 2020, 146, pp.104055. ⟨10.1016/j.orggeochem.2020.104055⟩. ⟨hal-02963254⟩
69 Consultations
74 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More