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Article Dans Une Revue Advanced Synthesis and Catalysis Année : 2020

Electrochemical Dearomative Dihydroxylation and Hydroxycyclization of Indoles

Résumé

We describe a simple and sustainable MgBr2-mediated electrochemical dearomative dihydroxylation and hydroxycyclization reactions of indoles with water. MgBr2 is used in substoichiometric amount and acts as an electrolyte and potentially as a redox mediator to indirectly oxidize the indole nucleus into a bromonium ion which is involved in the aforementioned reactions.

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Chimie
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Dates et versions

hal-02960497 , version 1 (12-11-2020)

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Ju Wu, Régis Guillot, Cyrille Kouklovsky, Guillaume Vincent. Electrochemical Dearomative Dihydroxylation and Hydroxycyclization of Indoles. Advanced Synthesis and Catalysis, 2020, 362 (8), pp.1712-1719. ⟨10.1002/adsc.202000158⟩. ⟨hal-02960497⟩
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