Electrochemical Dearomative Dihydroxylation and Hydroxycyclization of Indoles
Résumé
We describe a simple and sustainable MgBr2-mediated electrochemical dearomative dihydroxylation and hydroxycyclization reactions of indoles with water. MgBr2 is used in substoichiometric amount and acts as an electrolyte and potentially as a redox mediator to indirectly oxidize the indole nucleus into a bromonium ion which is involved in the aforementioned reactions.
Domaines
Chimie
Origine : Fichiers produits par l'(les) auteur(s)
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