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Article Dans Une Revue Chemical Communications Année : 2020

Manganese and rhenium-catalyzed selective reduction of esters to aldehydes with hydrosilanes

Résumé

The selective reduction of esters to aldehydes, via the formation of stable alkyl silyl acetals, was, for the first time, achieved with both manganese, -Mn(CO)- and rhenium -Re(CO)- catalysts in the presence of triethylsilane as reductant. These two methods provide a direct access to a large variety of aliphatic and aromatic alkyl silyl acetals (30 examples) and to the corresponding aldehydes (13 examples) upon hydrolysis. The reactions proceeded in excellent yields and high selectivity at room temperature under photo-irradiation conditions (LED, 365 nm, 40 W, 9 h).

Domaines

Chimie
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Dates et versions

hal-02959788 , version 1 (18-11-2020)

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Duo Wei, Ruqaya Buhaibeh, Yves Canac, Jean-Baptiste Sortais. Manganese and rhenium-catalyzed selective reduction of esters to aldehydes with hydrosilanes. Chemical Communications, 2020, 56 (78), pp.11617-11620. ⟨10.1039/d0cc03580g⟩. ⟨hal-02959788⟩
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