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Article Dans Une Revue Inorganics Année : 2020

Chiral Self-Sorting in Truxene-based Metallacages

Simon Séjourné
Antoine Labrunie
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Clément Dalinot
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Amina Benchohra
Magali Allain
Marc Sallé
Sébastien Goeb

Résumé

Two chiral face-rotating metalla-assembled polyhedra were constructed upon self-assembling achiral components, i.e., a tritopic ligand based on a truxene core (10,15-dihydro-5H-diindeno [1,2-a;1 ,2-c]fluorene) and two different hydroxyquinonato-bridged diruthenium complexes. Both polyhedra were characterized in solution as well as in the solid state by X-ray crystallography. In both cases, the self-sorting process leading to only two homo-chiral enantiomers was governed by non-covalent interactions between both truxene units that faced each other.
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Dates et versions

hal-02794371 , version 1 (07-12-2020)

Identifiants

Citer

Simon Séjourné, Antoine Labrunie, Clément Dalinot, Amina Benchohra, Vincent Carré, et al.. Chiral Self-Sorting in Truxene-based Metallacages. Inorganics, 2020, 8 (1), pp.1. ⟨10.3390/inorganics8010001⟩. ⟨hal-02794371⟩
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