We consider killed planar random walks on isoradial graphs. Contrary to the lattice case, isoradial graphs are not translation invariant, do not admit any group structure and are spatially non-homogeneous. Despite these crucial differences, we compute the asymptotics of the Martin kernel, deduce the Martin boundary and show that it is minimal. Similar results on the grid $\mathbb Z^d$ are derived in a celebrated work of Ney and Spitzer.