Carbohydrate binding through first- and second-sphere coordination within aromatic oligoamide metallofoldamers
Résumé
Aromatic oligoamide capsules that fold upon metal binding recognize carbohydrate guests in solution as evidenced by CD and NMR titrations. Crystallographic data reveals that, besides their structural role, metal ions also contribute to guest recognition through either first-or second-sphere coordination.
Domaines
Chimie de coordinationOrigine | Fichiers produits par l'(les) auteur(s) |
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