Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2- - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Chemical Communications Année : 2016

Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2-

Résumé

The mononuclear complex (Bu4N)2[ReIVCl4(CN)2].2DMA (DMA =N,N-dimethylacetamide) displays intricate magnetization dynamics, implying Orbach, direct, and Raman-type relaxation processes. The Orbach relaxation process is characterized by an energy barrier of 39 K (27 cm-1) that is discussed based on high-field electron paramagnetic resonance (EPR), inelastic neutron scattering and frequency domain THz EPR investigations.

Domaines

Matériaux

Dates et versions

hal-01394660 , version 1 (09-11-2016)

Identifiants

Citer

Xiaowen Feng, Jun-Liang Liu, Kasper S. Pedersen, Joscha Nehrkorn, Alexander Schnegg, et al.. Multifaceted magnetization dynamics in the mononuclear complex [ReIVCl4(CN)2]2-. Chemical Communications, 2016, 52, pp.12905-12908. ⟨10.1039/c6cc05473k⟩. ⟨hal-01394660⟩
55 Consultations
0 Téléchargements

Altmetric

Partager

Gmail Facebook X LinkedIn More