Multifaceted magnetization dynamics in the mononuclear complex [Re$^{IV}$Cl$_4$(CN)$_2$]$^{2-}$
Résumé
The mononuclear complex (Bu$_4$N)$_2$[Re$^{IV}$Cl$_4$(CN)$_2$].2DMA (DMA =N,N-dimethylacetamide) displays intricate magnetization dynamics, implying Orbach, direct, and Raman-type relaxation processes. The Orbach relaxation process is characterized by an energy barrier of 39 K (27 cm$^{-1}$) that is discussed based on high-field electron paramagnetic resonance (EPR), inelastic neutron scattering and frequency domain THz EPR investigations.
Domaines
Chimie de coordination| Origine | Publication financée par une institution |
|---|---|
| Licence |
