Researchers have proven with both theoretical and empirical studies that technologies could enhance learning. Meanwhile, technologies could also create barriers to the latter. Particularly, when the use of technologies causes security and privacy concerns, E-learning becomes less fruitful as the participants are too afraid to be exposed by what has been provided to help them learn in the first place. This paper presents a study on user's perception in using E-learning technologies and the relevant issues. The major contribution of this paper is the awareness-raising of security and privacy issues, which are often overlooked in the research efforts that implicate user tracking and personal data usage for instructional purposes.