Efficient amorphous platinum catalyst cluster growth on porous carbon: A combined Molecular Dynamics and experimental study - Archive ouverte HAL
Article Dans Une Revue Applied Catalysis B: Environmental Année : 2015

Efficient amorphous platinum catalyst cluster growth on porous carbon: A combined Molecular Dynamics and experimental study

Résumé

Amorphous platinum clusters supported on porous carbon have been envisaged for high-performance fuel cell electrodes. For this application, it is crucial to control the morphology of the Pt layer and the Pt - substrate interaction to maximize activity and stability. We thus investigate the morphology evolution during Pt cluster growth on a porous carbon substrate employing atomic scale molecular dynamics simulations. The simulations are based on the Pt-C interaction potential using parameters derived from Density Functional Theory and are found to yield a Pt cluster morphology similar to that observed in low loaded fuel cell electrodes prepared by plasma sputtering. Moreover, the simulations show amorphous Pt cluster growth in agreement with X-ray diffraction and Transmisson Electron Microscopy experiments on high performance low Pt content (10µgPt cm-2) loaded fuel cell electrodes and provide a fundamental insight in the cluster growth mechanism.
Fichier principal
Vignette du fichier
Ms_ApCatB_PBrault_R1_2014.pdf (1.27 Mo) Télécharger le fichier
Origine Fichiers produits par l'(les) auteur(s)
Loading...

Dates et versions

hal-01016051 , version 1 (27-06-2014)

Identifiants

Citer

Lu Xie, Pascal Brault, Christophe Coutanceau, Jean-Marc Bauchire, Amaël Caillard, et al.. Efficient amorphous platinum catalyst cluster growth on porous carbon: A combined Molecular Dynamics and experimental study. Applied Catalysis B: Environmental, 2015, 162, pp.21-26. ⟨10.1016/j.apcatb.2014.06.032⟩. ⟨hal-01016051⟩
150 Consultations
498 Téléchargements

Altmetric

Partager

More