The surfactant addition effect in the elaboration of electrodepositated NiP-SiC composite coatings - Archive ouverte HAL
Article Dans Une Revue Surface and Coatings Technology Année : 2007

The surfactant addition effect in the elaboration of electrodepositated NiP-SiC composite coatings

Résumé

In this work, NiP-SiC composite coatings were prepared by electrodeposition from a plating bath containing NiSO4*6H2O; NiCl2*6H2O; H3PO3; H3PO4; Na2 SO4 and SiC particles (average diameter of 600 nm) in suspension. Anionic surfactant (SDS -- sodium dodecyl sulfate, CH3 (CH2)11SO4Na) or cationic surfactant (CTAHS--cetyltrimethylammonium hidrogensulfate, C19H43NO4S) were also added to this suspension. The number of incorporated particles by area unit (αnp/A) was evaluated by image analysis of micrographs obtained by scanning electron microscopy SEM). It was observed that organic additive addition influences the incorporated SiC particles rate on the metallic matrix. Addition of organic additives such as SDS or CTAHS modifies the characteristic of suspensions. Depending on particle size organic additive addition can change the number of incorporated particles in deposits during growth of the matrix. Decrease of the incorporated particle amount with the increase of particle size was verified. The selective incorporation process is associated to the presence of organic additive and it was not dependent on surfactant charge.

Domaines

Matériaux
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Dates et versions

hal-00807804 , version 1 (04-04-2013)

Identifiants

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Célia de Fraga Malfatti, Hugo Marcelo Veit, Tiago Lemos Menezes, Jane Zoppas Ferreira, J.S. Rodriguês, et al.. The surfactant addition effect in the elaboration of electrodepositated NiP-SiC composite coatings. Surface and Coatings Technology, 2007, vol. 201, pp. 6318-6324. ⟨10.1016/j.surfcoat.2006.11.040⟩. ⟨hal-00807804⟩
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