Biobased grafted polyesters prepared by in situ ring-opening polymerization - Archive ouverte HAL
Article Dans Une Revue Reactive and Functional Polymers Année : 2011

Biobased grafted polyesters prepared by in situ ring-opening polymerization

Résumé

EVA-g-PLA and EVA-g-PCL copolymers were synthesized by in situ polymerization of c-caprolactone and lactide, in the presence of molten ethylene vinyl acetate (EVA) copolymer, using titanium phenoxide (Ti(OPh)(4)) as initiator. The materials prepared in a internal batch mixer were characterized by (1)H NMR, SEM, FTIR, rheology, DSC, TGA and SEC and the synthesized copolymers identified through selective extraction. The mechanical performance was characterized by tensile tests and the biodegradability by the biochemical oxygen demand method. The results indicated that approximately 11 wt.% of EVA-g-PCL and 8 wt.% of EVA-g-PLA copolymers were synthesized. Moreover, the increase of the Young modulus was higher for the sample containing EVA-g-PCL. This sample also exhibited the higher biodegradability (36%).

Dates et versions

hal-00649126 , version 1 (07-12-2011)

Identifiants

Citer

I. Moura, R. Nogueira, Véronique Bounor-Legaré, A. V. Machado. Biobased grafted polyesters prepared by in situ ring-opening polymerization. Reactive and Functional Polymers, 2011, pp.694-703. ⟨10.1016/j.reactfunctpolym.2011.03.012⟩. ⟨hal-00649126⟩
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