A two-state model analysis of the melting of sodium clusters: Insights in the enthalpy-entropy compensation - Archive ouverte HAL
Article Dans Une Revue EPL - Europhysics Letters Année : 2010

A two-state model analysis of the melting of sodium clusters: Insights in the enthalpy-entropy compensation

Sébastien Zamith
Fabien Chirot
Jean-Marc L'Hermite

Résumé

Experimental melting temperatures and associated latent heats of size-selected sodium clusters are analyzed in the frame of a two-state model of melting. The strong variations of these quantities as a function of size make clusters an excellent benchmark for testing speculative ideas about melting. The relation between cohesive energy of clusters and their latent heat of melting is demonstrated, and a correlation between cohesive energy and vibrational frequency in the solid state is found. It is shown that this relation may throw light on the enthalpy-entropy compensation, which is observed in a variety of systems undergoing a first-order phase transition. A relation is established between the Lindemann melting criterion, the variation of the vibrational frequency with the cohesive energy, and the enthalpy-entropy compensation.
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Dates et versions

hal-00530359 , version 1 (28-10-2010)

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Sébastien Zamith, Fabien Chirot, Jean-Marc L'Hermite. A two-state model analysis of the melting of sodium clusters: Insights in the enthalpy-entropy compensation. EPL - Europhysics Letters, 2010, 92 (1), pp.13004. ⟨10.1209/0295-5075/92/13004⟩. ⟨hal-00530359⟩
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