Transannular Rearrangement of Activated Lactams: Stereoselective Synthesis of Substituted Pyrrolidine-2,4-diones from Diketopiperazines - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Angewandte Chemie International Edition Année : 2007

Transannular Rearrangement of Activated Lactams: Stereoselective Synthesis of Substituted Pyrrolidine-2,4-diones from Diketopiperazines

Résumé

We describe herein the unprecedented reactivity of N-carboxy derivatives of 2,5-diketopiperazines (DKPs). The reaction of these derivatives under basic conditions led to novel substituted pyrrolidine-2,4-diones (1).

Domaines

Chimie organique

Dates et versions

hal-00359100 , version 1 (05-02-2009)

Identifiants

Citer

Daniel Farran, Isabelle Parrot, Jean Martinez, Georges Dewynter. Transannular Rearrangement of Activated Lactams: Stereoselective Synthesis of Substituted Pyrrolidine-2,4-diones from Diketopiperazines. Angewandte Chemie International Edition, 2007, 46, pp.7488-7490. ⟨10.1002/anie.200702132⟩. ⟨hal-00359100⟩
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