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Communication Dans Un Congrès Année : 2003

Synthesis and characterization of polymers for nonlinear optical applications

S. Legoupy
  • Fonction : Auteur
F. Legros
V. Montembault
Fabrice Odobel
Cyrille Monnereau
Errol Blart
  • Fonction : Auteur
  • PersonId : 840054
Dominique Bosc
  • Fonction : Auteur
  • PersonId : 833190
A. Goullet
  • Fonction : Auteur
J.-Y. Mevellec
  • Fonction : Auteur
  • PersonId : 1151046

Résumé

A difunctional NLO Azo-Dye chromophore has been synthesized and polymerization has been performed with a comonomer bearing a side-chain epoxy group. Deposition of the polymer on glass substrates was performed by spin-coating, resulting in uniform films up to 2 μm thickness. The orientation of the chromophore was performed under a "pin-to-plane" positive corona discharge followed by a heat- treatment in order to obtain reticulation of the films. Molecular orientation has been investigated using UV-Vis. and Raman spectroscopy. Poling of the films results in a decay of absorbance as well as in a blue shift of the spectrum. At the same time, the 1600 cm-1 band disappears from the Raman spectra, indicating orientation of the chromophores. Cross-linking has been studied by FTIR and all-optical poling and showed an improved stability of the electro-optic thin films.
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Dates et versions

hal-00147636 , version 1 (19-05-2007)

Identifiants

Citer

V. Boucher, Julien Cardin, Dominique Leduc, Raynald Seveno, Roger Le Ny, et al.. Synthesis and characterization of polymers for nonlinear optical applications. 3rd international conference on Advanced Optical Materials and Device (AOMD-3) [ http://www.fpd.lu.lv/AOMD3/ ], Aug 2003, Riga, Latvia. Vol.5122, pp.206-209, ⟨10.1117/12.515725⟩. ⟨hal-00147636⟩
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