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Article Dans Une Revue Journal of Magnetic Resonance Année : 2007

Spectral Editing in Solid-State MAS NMR Quadrupolar Nuclei using Selective Satellite Inversion

Résumé

A sensitivity enhancement method based on selective adiabatic inversion of a satellite transition has been employed in a (π/2)CT–(π)ST1–(π/2)CT spectral editing sequence to both enhance and resolve multisite NMR spectra of quadrupolar nuclei. In addition to a total enhancement of 2.5 times for spin 3/2 nuclei, enhancements up to 2.0 times is reported for the edited sites in a mixture of rubidium salts.

Domaines

Matériaux
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Dates et versions

hal-00122562 , version 1 (03-01-2007)

Identifiants

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K.K. Dey, S. Prasad, J. Ash, M. Deschamps, P.J. Grandinetti. Spectral Editing in Solid-State MAS NMR Quadrupolar Nuclei using Selective Satellite Inversion. Journal of Magnetic Resonance, 2007, 185, pp.237-241. ⟨10.1016/j.jmr.2006.12.013⟩. ⟨hal-00122562⟩
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