Hybrid catalysis for enantioselective Baeyer–Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules - Institut des Sciences Moléculaires de Marseille Accéder directement au contenu
Article Dans Une Revue Reaction Chemistry & Engineering Année : 2023

Hybrid catalysis for enantioselective Baeyer–Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules

Résumé

Taking advantage of the standalone capacity of the two-component flavoenzyme oxygenation module, we extended the scope of the pH and oxygen robust iridium complex, Cp*Ir(bpy-OMe)H + to drive enzymatic reactions from a low-cost hydride source.
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hal-04495554 , version 1 (23-03-2024)

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Robert Röllig, Caroline E Paul, Pierre Rousselot-Pailley, Selin Kara, Véronique Alphand. Hybrid catalysis for enantioselective Baeyer–Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules. Reaction Chemistry & Engineering, 2023, 8 (12), pp.3117-3123. ⟨10.1039/d3re00411b⟩. ⟨hal-04495554⟩
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