Hybrid catalysis for enantioselective Baeyer–Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules
Résumé
Taking advantage of the standalone capacity of the two-component flavoenzyme oxygenation module, we extended the scope of the pH and oxygen robust iridium complex, Cp*Ir(bpy-OMe)H + to drive enzymatic reactions from a low-cost hydride source.
Fichier principal
2023 Ir cplx.pdf (1.33 Mo)
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2023 Ir cplx SI.pdf (1.28 Mo)
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