Article Dans Une Revue Chemical Communications Année : 2025

Recent developments in high-pressure promoted cycloaddition reactions: experimental and theoretical perspectives

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Cycloadditions are fundamental transformations in the synthetic chemist's toolkit, though they can sometimes lead to disappointing results due to steric or electronic constraints. High-pressure conditions offer an effective alternative strategy for promoting these difficult cases, often reducing or eliminating the need for chemical catalysts. This review highlights recent advances in high-pressure-mediated cycloadditions, from both experimental and theoretical perspectives. The compilation emphasizes how high-pressure techniques are particularly well-suited to these transformations, enhancing efficiency while promoting greener, more sustainable chemistry.

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hal-05368608 , version 1 (17-11-2025)

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Nathan Noël, Rayhane Hammami, Laëtitia Chausset-Boissarie, Riccardo Spezia, Isabelle Chataigner. Recent developments in high-pressure promoted cycloaddition reactions: experimental and theoretical perspectives. Chemical Communications, 2025, 61 (82), pp.15953-15971. ⟨10.1039/D5CC04390E⟩. ⟨hal-05368608⟩
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