Article Dans Une Revue European Journal of Inorganic Chemistry Année : 2009

Spontaneous Reduction of High‐Spin Fe III Complexes Supported by Benzoic Hydrazide Derivative Ligands

Résumé

We report herein experimental evidence for the spontaneous reduction of new high‐spin iron(III) Fe III (L ( n ) ) 2 Cl, L complexes to new high‐spin iron(II) Fe II (HL ( n ) ) 2 Cl 2 mononuclear complexes. These processes were checked by EPR, cyclovoltammetric, and pseudo‐steady voltammetric studies. Crystal structures of three new complexes (one Fe III and two Fe II ) were obtained from RX single‐crystal diffraction.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

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Dates et versions

hal-05325801 , version 1 (22-10-2025)

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Citer

Nouri Bouslimani, Nicolas Clement, Clément Toussaint, Sophie Hameury, Philippe Turek, et al.. Spontaneous Reduction of High‐Spin Fe III Complexes Supported by Benzoic Hydrazide Derivative Ligands. European Journal of Inorganic Chemistry, 2009, 2009 (25), pp.3734-3741. ⟨10.1002/ejic.200900382⟩. ⟨hal-05325801⟩
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