Article Dans Une Revue Synthesis: Journal of Synthetic Organic Chemistry Année : 2003

The Preparation of Aliphatic Fluorinated Sulfoximines

Résumé

This work describes the preparation of an aliphatic series of the N-trifluoromethanesulfonyl-S-trifluoromethyl-S-sulfoximine group. The key step of the synthesis is the imination of fluorinated sulfoxides under experimental conditions, which avoid cleavage of the alkyl group. The formation of sulfoximines 6 and 15 allows the preparation of various fluorinated sulfoximines having strong electron withdrawing properties.

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Dates et versions

hal-05123440 , version 1 (20-06-2025)

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Emmanuel Magnier, Claude Wakselman. The Preparation of Aliphatic Fluorinated Sulfoximines. Synthesis: Journal of Synthetic Organic Chemistry, 2003, 2003 (04), pp.0565-0569. ⟨10.1055/s-2003-37651⟩. ⟨hal-05123440⟩

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