Article Dans Une Revue Coordination Chemistry Reviews Année : 2025

Highly efficient palladium-catalyzed carbonylation reactions of terpenes

Résumé

Palladium is a significantly appropriate tool to catalyze the functionalization of unsaturated substrates into oxygenated compounds containing one more carbon atom, essentially through carbonylation reaction. This contribution focuses on the natural compounds terpenes, in order to show that palladium complexes efficiently catalyze the introduction of one CO component in their frame. This functionalization allows the direct synthesis of esters, lactones, or amides according to the alcohol or amine nucleophile used. A palladium-hydride is generally the active species involved in this carbonylation reaction. The new synthesized compounds could be useful in fine chemistry.

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hal-05068408 , version 1 (15-05-2025)

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Abdelouahd Oukhrib, Ph. Kalck, Martine Urrutigoïty. Highly efficient palladium-catalyzed carbonylation reactions of terpenes. Coordination Chemistry Reviews, 2025, 531, pp.216453. ⟨10.1016/j.ccr.2025.216453⟩. ⟨hal-05068408⟩
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