Article Dans Une Revue ACS Organic & Inorganic Au Année : 2025

Red Light and Supersilane: A Novel Pathway for Hydrofunctionalizations and Giese Reactions

Résumé

Herein, we describe the photoredox activation of silanes under deep-red irradiation with or without osmium-based photocatalysts to generate silyl radicals. These radicals were further employed for achieving various reactivities previously unexplored in the red-light spectral region, such as hydrosilylation, hydrosulfonylation, and Giese reaction. Overall, the developed deep-red protocols allow for the preparation of a diverse array of high-value molecules.

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hal-05063330 , version 1 (12-05-2025)

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Aakanksha Gurawa, Marc Taillefer, Alexis Prieto. Red Light and Supersilane: A Novel Pathway for Hydrofunctionalizations and Giese Reactions. ACS Organic & Inorganic Au, 2025, ⟨10.1021/acsorginorgau.5c00032⟩. ⟨hal-05063330⟩
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