Article Dans Une Revue Journal of Organic Chemistry Année : 2023

Ir-Catalyzed Synthesis of Functionalized Pyrrolidines and Piperidines Using the Borrowing Hydrogen Methodology

Résumé

The Ir(III)-catalyzed synthesis of 3-pyrrolidinols and 4-piperidinols combining 1,2,4-butanetriol or 1,3,5-pentanetriol with primary amines was carried out. This borrowing hydrogen methodology was further extended to the sequential diamination of triols leading to amino-pyrrolidines and amino-piperidines.

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hal-04877154 , version 1 (01-12-2025)

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Malvina Larduinat, Jordan François, Maïwenn Jacolot, Florence Popowycz. Ir-Catalyzed Synthesis of Functionalized Pyrrolidines and Piperidines Using the Borrowing Hydrogen Methodology. Journal of Organic Chemistry, 2023, 88 (11), pp.7512-7517. ⟨10.1021/acs.joc.3c00329⟩. ⟨hal-04877154⟩
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