Assessing the Influence of Confinement on the Stability of Polyoxometalate-Functionalized Surfaces: A Soft Sequential Immobilization Approach for Electrochromic Devices
Résumé
A functionalization process has been developed and the experimental conditions optimized allowing the immobilization of first-row transition metal containing polyoxometalates (POMs) with the formula [M(H2O)P2W17O61] (n-10)-on transparent indium-tin oxide (ITO) electrodes for electrochromic applications. Both flat ITO grafted with 4-sulfophenyl moieties and sulfonate-functionalized vertically-oriented silica films on ITO have been used as electrode.
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