Article Dans Une Revue ACS Applied Materials & Interfaces Année : 2024

Assessing the Influence of Confinement on the Stability of Polyoxometalate-Functionalized Surfaces: A Soft Sequential Immobilization Approach for Electrochromic Devices

Résumé

A functionalization process has been developed and the experimental conditions optimized allowing the immobilization of first-row transition metal containing polyoxometalates (POMs) with the formula [M(H2O)P2W17O61] (n-10)-on transparent indium-tin oxide (ITO) electrodes for electrochromic applications. Both flat ITO grafted with 4-sulfophenyl moieties and sulfonate-functionalized vertically-oriented silica films on ITO have been used as electrode.

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hal-04727569 , version 1 (09-10-2024)

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Neus Vilà, Linh Nguyen, Jean-Christophe Lacroix, Xiaonan Sun, Alain Walcarius, et al.. Assessing the Influence of Confinement on the Stability of Polyoxometalate-Functionalized Surfaces: A Soft Sequential Immobilization Approach for Electrochromic Devices. ACS Applied Materials & Interfaces, 2024, 16 (20), pp.26521-26536. ⟨10.1021/acsami.4c01859⟩. ⟨hal-04727569⟩
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