Three Terminal Organic-Silicon Tandem Models - Archive ouverte HAL
Communication Dans Un Congrès Année : 2024

Three Terminal Organic-Silicon Tandem Models

Ahmed Nejim
Andrew Plews

Résumé

The search for ever higher efficiency solar cells is at present focussed on multijunction devices. In this field, there is enormous research on tandems consisting of a high bandgap top sub-cell coupled to a Si bottom sub-cell . An emerging top cell candidate is the organic solar cell, given recent impressive breakthroughs in efficiency and stability , thanks in part to non-fullerene ac-ceptors. In this context, we report on approaches to modelling organic solar cells for silicon / organic tandems. The device studied is the three-terminal selective band-offset tandem cell . This innovative design shown in figure 1a is based on the Si interdigitated back contact solar cell , which features a number of fabrication and operating advantages over four terminal and two terminal tandems . The higher gap organic top sub-cell consists of donor and acceptor organic phases in an absorber blend, contacted to hole and electron transport layers, which is in devel-opment within the French ANR project ORGANIST. The modelling of the organic sub-cell is the main focus of this presentation, and is investigated with increasing levels model complexity. The modelling of the complete tandem is first described with a simple first approximation which only considers idealised classic drift-diffusion phenomena of inorganic semiconductors, with optical and band structure data from current best estimates of suitable non-fullerene high bandgap organic solar cell materials . It is shown that this approach is sufficient to quantitatively predict tandem efficiencies with suitable approximations for optical and transport parameters. Figure 1b shows the resulting quantum efficiency of a preliminary 26% tandem without device optimisation, and with a non-textured Si IBC. Organic modelling is then developed from stand-ard open access models , by moving from the widespread effective medium approach treating the absorber blend as a homogeneous material, to a bulk heterojunction model where the accep-tor and donor organic phases are simulated separately. We conclude with lessons learned on the comparative benefits of the modelling approaches for the design and development of high effi-ciency organic solar cells.
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Dates et versions

hal-04681613 , version 1 (29-08-2024)

Identifiants

  • HAL Id : hal-04681613 , version 1

Citer

James P. Connolly, J Alvarez, Jean-Paul Kleider, Sylvain Chambon, Lionel Hirsch, et al.. Three Terminal Organic-Silicon Tandem Models. International Conference on Simulation of Organic Electronics and Photovoltaics, SimOEP 2024, Sep 2024, Winterthur, Switzerland. ⟨hal-04681613⟩
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