This study aims at reconstructing the paleostress history of the Outer (offshore) Kwanza basin (West African passive margin) and at comparing it to stress results acquired further north in the Congo basin. Three oriented borehole cores provided by TotalEnergies and reaching the syn-rift, Barremian-Aptian pre-salt carbonates offshore Angola were investigated. Paleopiezometry based on the Stylolite Roughness Inversion Technique (SRIT) and Calcite Twin Inversion Technique (CSIT) was combined with fracture analysis, U–Pb geochronology of carbonates and burial modelling to unravel the orientations and magnitudes of horizontal and vertical stresses affecting the pre-salt carbonates over time. Calcite twins were measured from a primary sparite matrix, and the inversion process unravelled a polyphase stress history, comprising ~ E-W and NE-SW extensional trends that we associate to the rifting (130-112 Ma) that led to the opening of the South Atlantic ocean. The ~ E-W extension is consistent with the early occurrence of N-S striking normal faults which developed in relation to the reactivation of inherited basement structures. This ~ E-W extension evolved during the Barremian-Aptian (?) into the dominant regional NE-SW extension marked by large-scale NW-SE striking normal faults. The stress history also comprises compressional and strike-slip stress regimes associated with a ~N-S trending σ1 which can be related to the transfer of orogenic stresses from the distant Africa-Eurasia plate boundary at ~67-60 Ma. Finally, compressional and strike-slip stress regimes associated with a ENE-WSW to ~E-W trending σ1 dominated since at least ~17-15 Ma (possibly ~34 Ma); they are interpreted as the expression of the mid-Atlantic ridge push. These (paleo)stress results are compared and combined with earlier paleostress reconstructions in the northern offshore Lower Congo basin (also belonging to the Central segment of the margin) and in the onshore Congo basin in order to refine the stress record and the timing of tectonic events since the early Cretaceous, thus providing unprecedented constraints on the tectonic history of the West Africa passive margin. This tectonic history includes both extensional and compressional events, and was driven mainly by far-field stresses, either gravitational or tectonic in origin, which are related to interactions between the African plate and surrounding plates.