Structural and conformational analysis of a biaryl phosphine integrating a calix[4]arene cavity. Can the phosphorus atom behave as an introverted donor? - Archive ouverte HAL Accéder directement au contenu
Article Dans Une Revue Dalton Transactions Année : 2023

Structural and conformational analysis of a biaryl phosphine integrating a calix[4]arene cavity. Can the phosphorus atom behave as an introverted donor?

Résumé

The conformational preference of a cavity-based biaryl phosphine, namely 5-(2-diphenylphosphinyl-phenyl)-25,26,27,28-tetrapropyloxycalix[4]arene (L) has been investigated by density functional theory calculations. The analysis showed that the barrier to rotation about the C–C axle of the biaryl unit is only 10.7 kcal mol−1, this rendering possible access to conformers of two types, those in which the P lone pair sits at the cavity entrance and points to the calixarene interior, others with a more open structure where the P atom is located outside the cavity. As revealed by a single crystal X-ray diffraction study, the biaryl phosphine appears virtually as an atropisomer in the solid state in which the phosphorus atom lies totally out of the cavity defined by the four phenoxy rings.
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hal-04636144 , version 1 (05-07-2024)

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Christophe Gourlaouen, Fethi Elaieb, Eric Brenner, Dominique Matt, Jack Harrowfield, et al.. Structural and conformational analysis of a biaryl phosphine integrating a calix[4]arene cavity. Can the phosphorus atom behave as an introverted donor?. Dalton Transactions, 2023, 52 (27), pp.9202 - 9207. ⟨10.1039/d3dt00612c⟩. ⟨hal-04636144⟩
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